At St Francis Xavier’s Catholic Primary School Arncliffe, all staff work collaboratively within their roles to achieve the best possible outcomes for our community.
| Principal | Mrs Debra Heckenberg |
| Assistant Principal | Mrs Ashley Marszalek |
| Instructional Specialist | Miss Katie Boyle |
| Religious Education Coordinator | Mrs Zoe Copper |
| Coordinator | Mrs Rose Chalker |
| Coordinator | Miss Sally Hay |
| Kindergarten Teacher (KF) | MIss Chauntelle Cartwright |
| Kindergarten Teacher (KM) | Miss Sally Hay |
| Kindergarten Teacher (KM) | Mrs Ashley Marszalek |
| Year 1 Teacher (1F) | Miss Alicia Aslanidis |
| Year 1 Teacher (1M) | Miss Tia Chaanine |
| Year 2 Teacher (2F) | Mrs Zoe Copper |
| Year 2 Teacher (2F) | Mrs Natalie Chow |
| Year 2 Teacher (2M) | Miss Sinead Egan |
| Year 3 Teacher (3F) | Miss Stacey Drossos |
| Year 3 Teacher (3M) | Mrs Rose Chalker |
| Year 3 Teacher (3M) | Mrs Natalie Chow |
| Year 4 Teacher (4F) | Mrs Jasmine Weidemier |
| Year 4 Teacher (4M) | Miss Sophia Gallina |
| Year 5 Teacher (5F) | Miss Riona Walsh |
| Year 5 Teacher (5M) | Miss Stephanie Markos |
| Year 6 Teacher (6F) | Miss Deni Patalis |
| Year 6 Teacher (6M) | Miss Katie Boyle |
| Year 6 Teacher (6M) | Mrs Genevieve Husband |
| PPT Teacher | Ms Joanne Giardina |
| PPT Teacher | Ms Dianne wells |
| Diverse Learning Needs | Mrs Ashley Marszalek |
| Literacy Intervention/ EALD Teacher | Miss Katherine Gavrielatos |
| Family Educator | Mrs Marisa Candaten |
| Administration Manager | Ms Connie Fiorini |
| Administration Assistant | Ms Kim Mahoney |
| Learning Support | Mrs Aleksandra Stojanovski |
| Learning Support | Mrs Andie Fitzgerald |
| Learning Support | Mrs Elizabeth Hunt |
| Learning Support | Miss Michelle Barbarigos |
| Learning Support | Miss Nastasha Bougesis |
| Learning Support | Miss Isabella Touma |
| Learning Support | Miss Jessica Azzi |
| Learning Support | Miss Bridget Azar |
| Learning Support | Miss Caitlin Gaffney |