At St Francis Xavier’s Catholic Primary School Arncliffe, all staff work collaboratively within their roles to achieve the best possible outcomes for our community.
| Principal | Mrs Debra Heckenberg |
| Assistant Principal | Mrs Ashley Marszalek |
| Religious Education Coordinator | Miss Victoria Kalamvokis |
| Coordinator | Miss Natalie Loizou |
| Coordinator | Miss Haylee Baird |
| Kindergarten Teacher (KF) | Mrs Rose Chalker |
| Kindergarten Teacher (KM) | Miss Sally Hay |
| Year 1 Teacher (1F) | Miss Deni Patalis |
| Year 1 Teacher (1M) | Miss Zoe Blight |
| Year 2 Teacher (2F) | Miss Katherine Gavrielatos |
| Year 2 Teacher (2M) | Mrs Samantha Perri |
| Year 3 Teacher (3M) | Miss Sophia Gallina |
| Year 3 Teacher (3F) | Miss Haylee Baird |
| Year 3 Teacher (3F) | Mrs Ashley Marszalek |
| Year 4 Teacher (4F) | Miss Jessica Stojanovska |
| Year 4 Teacher (4M) | Mrs Vanessa Del Monte |
| Year 5 Teacher | Mrs Victoria Kalamvokis |
| Year 5 Teacher | Mrs Natalie Chow |
| Year 6 Teacher | Miss Natalie Loizou |
| Year 6 Teacher | Mrs Natalie Chow |
| PPT Teacher | Miss Isabella Russell |
| PPT Teacher | Miss Cherre Ho |
| Diverse Learning Needs | Mrs Ashley Marszalek |
| Reading Recovery& EAL/D Teacher | Ms Dianne Wells |
| Family Educator | Mrs Marisa Candaten |
| Administration Manager | Ms Connie Fiorini |
| Administration Assistant | Ms Kim Mahoney |
| Large Class Support Teacher | Miss Isabella Russell |
| Learning Support | Mrs Aleksandra Stojanovski |
| Learning Support | Mrs Andie Fitzgerald |
| Learning Support | Mrs Dorothy Galloway |
| Learning Support | Mrs Elizabeth Hunt |
| Learning Support | Miss Michelle Barbarigos |